PHOTOCHEMICAL ISOMERIZATION OF 1-GERMA-2,4-CYCLOHEXADIENES

Citation
K. Mochida et al., PHOTOCHEMICAL ISOMERIZATION OF 1-GERMA-2,4-CYCLOHEXADIENES, Chemistry Letters, (10), 1994, pp. 1961-1962
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ISSN journal
03667022
Issue
10
Year of publication
1994
Pages
1961 - 1962
Database
ISI
SICI code
0366-7022(1994):10<1961:PIO1>2.0.ZU;2-#
Abstract
Tetraphenylgermacyclohexadiene photochemically isomerized to the 4-vin yl-germacyclobutene. In contrast, diphenylgermacyclohexadiene remained unchanged on irradiation in benzene, but in the presence of methanol it was converted to the methoxy-germane probably through the 1-germahe xatriene intermediate.