EPR LINESHAPE OF MN IN BCCD SINGLE-CRYSTALS IN THE INCOMMENSURATE PHASE

Citation
R. Heidler et al., EPR LINESHAPE OF MN IN BCCD SINGLE-CRYSTALS IN THE INCOMMENSURATE PHASE, Chemical physics letters, 229(1-2), 1994, pp. 143-146
Citations number
10
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
229
Issue
1-2
Year of publication
1994
Pages
143 - 146
Database
ISI
SICI code
0009-2614(1994)229:1-2<143:ELOMIB>2.0.ZU;2-R
Abstract
For the interpretation of the EPR lineshape of incommensurate phases t here exist many theoretical models. We suppose a simple physical model to interpret the lineshape of the Mn2+ EPR spectrum of the first inco mmensurate phase of betaine calcium chloride dihydrate (BCCD) and disc uss it in comparison with other models. Furthermore, we investigate th e critical behavior of BCCD at the normal to incommensurate phase tran sition on the basis of our model. The influence of the Mn2+ impurities on the phase sequence of BCCD is investigated by dielectric measureme nts.