SYNTHESIS, X-RAY-ANALYSIS, AND ELECTROCHEMICAL STUDY OF SOME MANGANESE CARBONYL DERIVATIVES WITH 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, DPPFE

Authors
ONAKA S HAGA MA TAKAGI S OTSUKA M MIZUNO K
Citation
S. Onaka et al., SYNTHESIS, X-RAY-ANALYSIS, AND ELECTROCHEMICAL STUDY OF SOME MANGANESE CARBONYL DERIVATIVES WITH 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, DPPFE, Bulletin of the Chemical Society of Japan, 67(9), 1994, pp. 2440-2446
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
67
Issue
9
Year of publication
1994
Pages
2440 - 2446
Database
ISI
SICI code
0009-2673(1994)67:9<2440:SXAESO>2.0.ZU;2-R
Abstract
Synthesis and X-ray structure analyses were carried out for fac-cis-[M nCl(CO)3dppfe] and fac-cis-[MnH-(CO)3dppfe], and a cyclic voltammetric study was made for a series of manganese carbonyl derivatives with 1, 1'-bis(diphenylphosphino)ferrocene (dppfe), including these new compou nds. Unusually a low oxidation potential for the Mn site is revealed f or [Mn(MeCp)(CO)dppfe]. A good correlation between nu(CO) and the oxid ation potential for the Mn atom has been clarified.