S. Onaka et al., SYNTHESIS, X-RAY-ANALYSIS, AND ELECTROCHEMICAL STUDY OF SOME MANGANESE CARBONYL DERIVATIVES WITH 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, DPPFE, Bulletin of the Chemical Society of Japan, 67(9), 1994, pp. 2440-2446
Synthesis and X-ray structure analyses were carried out for fac-cis-[M
nCl(CO)3dppfe] and fac-cis-[MnH-(CO)3dppfe], and a cyclic voltammetric
study was made for a series of manganese carbonyl derivatives with 1,
1'-bis(diphenylphosphino)ferrocene (dppfe), including these new compou
nds. Unusually a low oxidation potential for the Mn site is revealed f
or [Mn(MeCp)(CO)dppfe]. A good correlation between nu(CO) and the oxid
ation potential for the Mn atom has been clarified.