SYNTHESES AND PROPERTIES OF FERROCENYLETHYNYL TRANSITION-METAL COMPLEXES OF PLATINUM, PALLADIUM, AND NICKEL

Authors
ONITSUKA K TAO XQ SONOGASHIRA K
Citation
K. Onitsuka et al., SYNTHESES AND PROPERTIES OF FERROCENYLETHYNYL TRANSITION-METAL COMPLEXES OF PLATINUM, PALLADIUM, AND NICKEL, Bulletin of the Chemical Society of Japan, 67(9), 1994, pp. 2611-2613
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
67
Issue
9
Year of publication
1994
Pages
2611 - 2613
Database
ISI
SICI code
0009-2673(1994)67:9<2611:SAPOFT>2.0.ZU;2-I
Abstract
Square planar ferrocenylethynyl transition metal complexes M(C=CFc)2(P R3)2 (M = Pt, Pd, Ni; Fc = (C5H4)Fe(C5H5)) were prepared by the reacti on of MCl2(PR3)2 with ethynylferrocene in the presence of a CuI cataly st in diethylamine, and characterized by spectral analyses. An interac tion between transition metals and an iron atom was studied by using e lectronic spectroscopy.