CHOOSING REFERENCE SAMPLES FOR EPR CONCENTRATION MEASUREMENTS .2. SYSTEMS OF S=1

Citation
Vy. Nagy et Dp. Sokolov, CHOOSING REFERENCE SAMPLES FOR EPR CONCENTRATION MEASUREMENTS .2. SYSTEMS OF S=1, Analytica chimica acta, 339(1-2), 1997, pp. 13-29
Citations number
10
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032670
Volume
339
Issue
1-2
Year of publication
1997
Pages
13 - 29
Database
ISI
SICI code
0003-2670(1997)339:1-2<13:CRSFEC>2.0.ZU;2-P
Abstract
The papers of this series provide tabulated values that characterize t he specific intensity of EPR signals (signal area per paramagnetic cen ter) for a wide range of paramagnetic species of various classes. Thes e data enable one to choose a reference material producing an EPR sign al close in specific intensity to the signal of the species to be quan titated in the unknown or to determine a correction factor when the sp ecific intensities of the two signals are substantially different. The tabulated values comprise transition probabilities and the derivative s of the resonance fields with respect to the frequency obtained by ex act diagonalization of spin Hamiltonian matrices; they can be used in field-swept X-band EPR quantitations of solids. This part covers the S =1 paramagnetic centers in cubic, axial, and orthorhombic crystal fiel ds.