LIME-CONCENTRATE PROCESS FOR ROASTING OF COPPER-BEARING SULFIDES .2. EFFECT OF SULFIDE - LIME RATIO, AIR-FLOW RATE, PELLET SIZE AND POROSITY ON REACTION-KINETICS
Bs. Terry et al., LIME-CONCENTRATE PROCESS FOR ROASTING OF COPPER-BEARING SULFIDES .2. EFFECT OF SULFIDE - LIME RATIO, AIR-FLOW RATE, PELLET SIZE AND POROSITY ON REACTION-KINETICS, Transactions - Institution of Mining and Metallurgy. Section C. Mineral processing & extractive metallurgy, 103, 1994, pp. 30000201-30000209
The air-roasting of pellets consisting of copper-iron sulphides and li
me has been investigated to explore the possibility of developing a me
tal-production process that eliminates the emission of sulphur dioxide
gas. The effects of pellet porosity, sulphide:lime ratio, air flow ra
te and pellet size on reaction rates and reaction products were invest
igated. A thermogravimetric technique was used under air atmosphere an
d the weight gain of a pelletized sample was used to identify and stud
y the phases present in the reaction products. The experimental result
s indicate that at 500-degrees-C a completely reacted pellet can be pr
oduced in about 50 min with a very low emission of sulphur dioxide. Th
e reaction products are primarily CaSO4, Fe2O3, CuSO4 and CuO.CuSO4, a
lthough some CaS may also be produced.