Dj. Wilson et al., SOIL CLEANUP BY IN-SITU AERATION .20. MASS-TRANSPORT OF VOLATILE ORGANICS IN WET ACTIVATED CARBON, Separation science and technology, 29(16), 1994, pp. 2073-2095
A mathematical model for the adsorption of volatile organic compounds
(VOCs) from wet gas streams by granular activated carbon columns is de
veloped, and modeling results are discussed. Capillary condensation of
water in the carbon pores is found to have a very damaging effect on
the rate of VOC adsorption, since diffusion rates of VOCs into the por
es are greatly reduced. Implications of the results for the operation
of soil vapor extraction systems for the remediation of hazardous wast
e sites are discussed, and suggestions are made on how to deal with th
e problem.