NOVEL HYDROPEROXIDATION OF THE ALPHA-POSITION IN PYRIDOXYLIDENE-AMINOACID-SCHIFF BASE-COBALT COMPLEX BY HYDROGEN-PEROXIDE

Authors
JITSUKAWA K YAMAMOTO T ATSUMI T MASUDA H EINAGA H
Citation
K. Jitsukawa et al., NOVEL HYDROPEROXIDATION OF THE ALPHA-POSITION IN PYRIDOXYLIDENE-AMINOACID-SCHIFF BASE-COBALT COMPLEX BY HYDROGEN-PEROXIDE, Journal of the Chemical Society, Chemical Communications, (20), 1994, pp. 2335-2336
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
20
Year of publication
1994
Pages
2335 - 2336
Database
ISI
SICI code
0022-4936(1994):20<2335:NHOTAI>2.0.ZU;2-T
Abstract
The reaction of pyridoxylidene-L-phenylalanine with Co-II ion in the p resence of H2O2 generates a novel Co-III ternary complex, yridoxyliden e-alpha-hydroperoxyphenylalaninato)]-, which has been characterized on the basis of the analysis of its H-1 NMR, positive-ion FAB MS and X-r ay structure.