HYDROTHERMAL SYNTHESIS OF SINGLE-CRYSTALS OF MG2[BE3(PO4)(3)(OH)].6H2O - THE ONE-DIMENSIONALLY INFINITE, CHIRAL, POLAR POLYANION [BE3(PO4)(3)(OH)](N)(4N-)

Authors
ROBL C GOBNER V
Citation
C. Robl et V. Gobner, HYDROTHERMAL SYNTHESIS OF SINGLE-CRYSTALS OF MG2[BE3(PO4)(3)(OH)].6H2O - THE ONE-DIMENSIONALLY INFINITE, CHIRAL, POLAR POLYANION [BE3(PO4)(3)(OH)](N)(4N-), Journal of the Chemical Society, Chemical Communications, (20), 1994, pp. 2345-2346
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
20
Year of publication
1994
Pages
2345 - 2346
Database
ISI
SICI code
0022-4936(1994):20<2345:HSOSOM>2.0.ZU;2-D
Abstract
Single crystals of Mg-2[Be-3(PO4)(3)(OH)].6H(2)O are grown hydrotherma lly and characterized by X-ray structure analysis, which proves BeO3(O H) and PO4 tetrahedra are linked by common corners to establish a one- dimensionally infinite, chiral, polar polyanion of composition [Be-3(P O4)(3)(OH)](4n-)(n) with nearly 1 nm diameter extending parallel to [0 01].