INSERTION VERSUS ELIMINATION IN THE REACTION OF BU(T)NC WITH A AZASILAVANADACYCLOBUTANE RING SUPPORTED BY HEXAMETHYLSILAZANATE LIGAND

Authors
BERNO P GAMBAROTTA S
Citation
P. Berno et S. Gambarotta, INSERTION VERSUS ELIMINATION IN THE REACTION OF BU(T)NC WITH A AZASILAVANADACYCLOBUTANE RING SUPPORTED BY HEXAMETHYLSILAZANATE LIGAND, Journal of the Chemical Society, Chemical Communications, (20), 1994, pp. 2419-2421
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
20
Year of publication
1994
Pages
2419 - 2421
Database
ISI
SICI code
0022-4936(1994):20<2419:IVEITR>2.0.ZU;2-R
Abstract
Reaction of the azasilavanadacyclobutane ring of the monomeric [V{(Me( 3)Si)(2)N}{CH(2)SiMe(2)N(SiMe(3))}(py)] with isonitrile gave insertion and ring expansion, while the same reaction carried out with the meta llacycle of the meric[V{(Me(3)Si)(2)N}{CH(2)SiMe(2)N{SiMe(3))}](2) for med an ionic and tetravalent [V{(Me(3)Si)(2)N}(3)]CN complex.