O[2,3-B]-PYRIDINE]ETA(5)-CYCLOPENTADIENYL)IRON(II) HEXAFLUOROPHOSPHATE

Authors
PIORKO A CHRISTIE S ZAWOROTKO MJ
Citation
A. Piorko et al., O[2,3-B]-PYRIDINE]ETA(5)-CYCLOPENTADIENYL)IRON(II) HEXAFLUOROPHOSPHATE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1544-1545
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
10
Pages
1544 - 1545
Database
ISI
SICI code
0108-2701(1994)50:<1544:OH>2.0.ZU;2-7
Abstract
The structure of ino[2,3-b]pyridine](eta5-cyclopentadienyl)iron(II) he xafluorophosphate, [Fe(C5H5)(C11H7NO2)]PF6, has been studied. The dihe dral angle between the benzene and pyridine rings of the ligand system is 177.4(3)-degrees; the benzene and cyclopentadienyl rings are nearl y parallel [dihedral angle 1.3(4)-degrees]. The Fe atom is closer to t he benzene ring [1.542(4) angstrom] than to the cyclopentadienyl (Cp) ring [1.652(5) angstrom] and it is located within the fold of the hete rocyclic ligand.