SYNTHESIS, STRUCTURE AND SPECTROSCOPIC PROPERTIES OF DIMETHYLAMMONIUMLANTHANIDE TETRAKIS(N,N-DIMETHYLDITHIOCARBAMATE)

Authors
SU CY TAN MY TANG N GAN XM ZHANG ZF XUE QJ YU KB
Citation
Cy. Su et al., SYNTHESIS, STRUCTURE AND SPECTROSCOPIC PROPERTIES OF DIMETHYLAMMONIUMLANTHANIDE TETRAKIS(N,N-DIMETHYLDITHIOCARBAMATE), Polyhedron, 16(10), 1997, pp. 1643-1650
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
10
Year of publication
1997
Pages
1643 - 1650
Database
ISI
SICI code
0277-5387(1997)16:10<1643:SSASPO>2.0.ZU;2-T
Abstract
Trivalent lanthanide complexes of the type [Ln(Me(2)Dtc)(4)]H(2)NMe(2) (Ln = La, Pr-Nd, Sm-Ho; Me(2)Dtc = N,N-dimethyldithiocarbamate) have been prepared and characterized by means of elemental analyses, IR spe ctra, electronic spectra, H-1 NMR spectra and conductivity measurement s. The X-ray crystal and molecular structure of the neodymium complex has been determined from diffractometer data. There are two independen t [Nd(Me(2)Dtc)(4)]H(2)NMe(2) monomers in each unit cell; the metal co ordination number is 8. Spectroscopic properties of the complexes are discussed. (C) 1997 Elsevier Science Ltd.