METAL SUBSTITUTION-REACTION IN THE CLUSTER (MU-H)(2)FE-3(MU(3)-SE)(CO)(9) .4. CRYSTAL AND MOLECULAR-STRUCTURE OF 3)-SE)(2)(MU(3)-CO)(MU-CO)(CO)(5)(ETA(5)-C5H5)(2)]

Authors
KONCHENKO SN VIROVETS AV PODBEREZSKAYA NV
Citation
Sn. Konchenko et al., METAL SUBSTITUTION-REACTION IN THE CLUSTER (MU-H)(2)FE-3(MU(3)-SE)(CO)(9) .4. CRYSTAL AND MOLECULAR-STRUCTURE OF 3)-SE)(2)(MU(3)-CO)(MU-CO)(CO)(5)(ETA(5)-C5H5)(2)], Polyhedron, 16(10), 1997, pp. 1689-1691
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
10
Year of publication
1997
Pages
1689 - 1691
Database
ISI
SICI code
0277-5387(1997)16:10<1689:MSITC(>2.0.ZU;2-K
Abstract
The reaction of [(mu-H)(2)Fe-3(mu(3)-Se)(CO)(9)] with [CpW(CO)(3)](2) (Cp = eta(5)-C5H5) has been reinvestigated. In addition to tetrahedral heterometal clusters described previously the minor product [Fe2W2(mu (3)-Se)(2)(mu(3)-CO)(mu-CO)(CO)(5)Cp(2)] has been isolated. Its crysta l and molecular structure has been determined by X-ray methods. (C) 19 97 Elsevier Science Ltd.