PREPARATION AND SYNTHETIC UTILITY OF MCL(4)(ME(2)NCH(2)CH(2)NME(2))(2), WHERE M IS URANIUM OR THORIUM

Authors
EDWARDS PG WEYDERT M PETRIE MA ANDERSEN RA
Citation
Pg. Edwards et al., PREPARATION AND SYNTHETIC UTILITY OF MCL(4)(ME(2)NCH(2)CH(2)NME(2))(2), WHERE M IS URANIUM OR THORIUM, Journal of alloys and compounds, 213, 1994, pp. 11-14
Citations number
8
Categorie Soggetti
Chemistry Physical","Metallurgy & Mining","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
213
Year of publication
1994
Pages
11 - 14
Database
ISI
SICI code
0925-8388(1994)213:<11:PASUOM>2.0.ZU;2-B
Abstract
UCl4 or ThCl4 dissolves in a solution of Me(2)NCH(2)CH(2)NMe(2) (tmed) in toluene to give green UCl4(tmed)(2) or colorless ThCl4(tmed)(2). A nion metathesis with Me(3)SiBr or Me(3)SiI gives UBr4(tmed)(x) or UI4( tmed)(x), where x lies between 1 and 2. The tmed complexes are useful synthons for other ligand complexes, as well as for (MeC(5)H(4))(3)ThC lor (MeC(5)H(4))(4)Th.