Authors
Citation
Jc. Krupa et al., OPTICAL SPECTROSCOPIC STUDIES OF URANYL CHLORIDE UO2CL2, Journal of alloys and compounds, 213, 1994, pp. 471-474
Citations number
20
Categorie Soggetti
Chemistry Physical","Metallurgy & Mining","Material Science
Journal title
ISSN journal
09258388
Volume
213
Year of publication
1994
Pages
471 - 474
Database
ISI
SICI code
0925-8388(1994)213:<471:OSSOUC>2.0.ZU;2-2
Abstract
The first part of this work concerns essentially a qualitative energy
level diagram of UO2Cl2 deduced from analysis of absorption and emissi
on optical spectra recorded at low temperature. It describes the energ
y spacing of unoccupied orbitals. In the second part, the configuratio
n coordinate model is used to explain successfully the shape of broadb
and transitions which are attributed to electron transfer from the las
t occupied orbital to orbitals showing a large 6d character.