Observations of the trailing hemisphere of Io made with the Faint Obje
ct Spectrograph of the Hubble Space Telescope in March 1992 have resul
ted in the first detection of atmospheric SO2 absorption bands in the
ultraviolet. These observations represent only the third positive mean
s of detection of what is widely believed to be Io's primary atmospher
ic constituent. Below approximately 2130 angstrom the geometric albedo
of the satellite is dominated by SO2 gas absorption band signatures,
which have been analyzed using models that include the effects of opti
cal thickness, temperature, and spatial distribution. The disk-integra
ted HST data cannot resolve the spatial distribution, but it is possib
le to define basic properties and set constraints on the atmosphere at
the time of the observations. Hemispheric atmospheres with average co
lumn density N = 6-10 x 10(15) cm-2 and T(gas) = 110-500 K fit the dat
a, with preference for temperatures of approximately 200-250 K. Better
fits are found as the atmosphere is spatially confined, with a limit
of approximately 8% hemispheric areal coverage and N almost-equal-to 3
x 10(17) cm-2 with colder 110-250 K temperatures. A dense (N greater-
than-or-equal-to 10(16) cm-2), localized component of SO2 gas, such as
that possibly associated with active volcanoes, can generate the obse
rved spectral contrast only when the atmosphere is cold (110 K) and an
extended component such as Pele is included. The combination of a den
se, localized atmosphere with a tenuous component (N < 10(16) cm-2, ei
ther patchy or extended) also fits the data. In all cases the best fit
models imply a disk-averaged column density larger than exospheric bu
t approximately 10-30 times less than the previous upper limit from ne
ar-UV observations. (C) 1994 Academic Press, Inc.