Kt. Li, SYNTHESIS OF POLY(2,6-DIMETHYL-1,4-PHENYLENE ETHER) CATALYZED BY COPPER-DIAMINE SYSTEM, Journal of applied polymer science, 54(9), 1994, pp. 1339-1351
Oxidative polymerization of 2,6-dimethylphenol to poly(2,6-dimethyl-1,
4-phenylene ether) (PPE) was studied in a high-pressure batch reactor
using a copper-diamine catalyst. In the presence of air, the effect of
monomer sources, catalyst formulation (copper salts, ligands, surfact
ant), and reaction conditions (air flow rate and pressure, temperature
, agitation, monomer and catalyst concentrations) on the catalyst perf
ormance was investigated. The sensitivity of PPE molecular weight and
the sensitivity of polymerization rates to these factors were found to
be quite different, indicating that little correlation existed betwee
n the PPE molecular weight and the 2,6-DMP polymerization rates. Mecha
nical test showed that the PPE produced with the copper-diamine cataly
st had modulus significantly higher than that produced with the copper
-dibutylamine catalyst system. (C) 1994 John Wiley & Sons, Inc.