3-(ALKYLTHIO)-1,2-BIS(SILOXY)-3-BUTENES AS EFFICIENT CHIRALITY TRANSFERRED BUILDING-BLOCKS

Citation
K. Masuya et al., 3-(ALKYLTHIO)-1,2-BIS(SILOXY)-3-BUTENES AS EFFICIENT CHIRALITY TRANSFERRED BUILDING-BLOCKS, Tetrahedron letters, 35(43), 1994, pp. 7965-7968
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
43
Year of publication
1994
Pages
7965 - 7968
Database
ISI
SICI code
0040-4039(1994)35:43<7965:3AECT>2.0.ZU;2-M
Abstract
In the presence of Me(2)AlCl, reactions of the title compounds with a variety of aldehydes proceeded with high efficacy of chirality transfe r to give the corresponding optically pure ene adducts, which could be converted to the gamma-lactones, eg., rove beetle pheromone.