PREPARATION OF DIMETHYL CARBONATE FROM METHANOL AND CARBON-DIOXIDE INTHE PRESENCE OF ORGANOTIN COMPOUNDS

Citation
J. Kizlink et I. Pastucha, PREPARATION OF DIMETHYL CARBONATE FROM METHANOL AND CARBON-DIOXIDE INTHE PRESENCE OF ORGANOTIN COMPOUNDS, Collection of Czechoslovak Chemical Communications, 59(9), 1994, pp. 2116-2118
Citations number
4
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
59
Issue
9
Year of publication
1994
Pages
2116 - 2118
Database
ISI
SICI code
0010-0765(1994)59:9<2116:PODCFM>2.0.ZU;2-6
Abstract
Dibutyltin dialkoxides react with methanol and carbon dioxide to give dimethyl carbonate in 60 to 220 mole % yields with respect to the orga notin compound. The higher yields of the carbonate (150 up to 330 mole %) have been achieved with the use of chemical scavengers of the reac tion water.