BICYCLO[3.2.1]OCTENONES AS BUILDING-BLOCKS IN NATURAL-PRODUCTS SYNTHESIS .3. TOTAL SYNTHESIS OF (+ -)-10-DEOXYGENIPOSIDE AGLUCONE/

Authors
HSU LF CHANG NC
Citation
Lf. Hsu et Nc. Chang, BICYCLO[3.2.1]OCTENONES AS BUILDING-BLOCKS IN NATURAL-PRODUCTS SYNTHESIS .3. TOTAL SYNTHESIS OF (+ -)-10-DEOXYGENIPOSIDE AGLUCONE/, Journal of the Chinese Chemical Society, 41(5), 1994, pp. 609-611
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of the Chinese Chemical Society → ACNP
ISSN journal
00094536
Volume
41
Issue
5
Year of publication
1994
Pages
609 - 611
Database
ISI
SICI code
0009-4536(1994)41:5<609:BABINS>2.0.ZU;2-7
Abstract
The title compound was synthesized from bicyclo[3.2.1]octenone 1 in si x steps and in overall yield 59%. Photochemical rearrangement of beta, gamma-unsaturated enone 1 is the key step.