BICYCLO[3.2.1]OCTENONES AS BUILDING-BLOCKS IN NATURAL PRODUCT SYNTHESIS .4. FORMAL SYNTHESIS OF (+ -)-HYDROXYLOGANIN AGLUCONE/

Authors
CHANG CP YIN WK CHANG NC
Citation
Cp. Chang et al., BICYCLO[3.2.1]OCTENONES AS BUILDING-BLOCKS IN NATURAL PRODUCT SYNTHESIS .4. FORMAL SYNTHESIS OF (+ -)-HYDROXYLOGANIN AGLUCONE/, Journal of the Chinese Chemical Society, 41(5), 1994, pp. 613-616
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chinese Chemical Society → ACNP
ISSN journal
00094536
Volume
41
Issue
5
Year of publication
1994
Pages
613 - 616
Database
ISI
SICI code
0009-4536(1994)41:5<613:BABINP>2.0.ZU;2-J
Abstract
A formal synthesis of (+/-)-hydroxyloganin aglucone from bicyclol3.2.1 ]octenone 1 is described. Ring opening of )-1-phenylthiotricyclo[4.2.1 .0(3,7)]non-4-en-2-one 14 with potassium hydroxide is the key reaction .