E. Gorecka et al., X-RAY STUDIES OF THE HEXATIC PHASE IN LIQUID-CRYSTALS WITH A CRYSTAL-B-HEXATIC-B-SMECTIC-A PHASE SEQUENCE, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 50(4), 1994, pp. 2863-2867
Free-standing monodomain thick films of three liquid crystalline compo
unds were examined by x-ray scattering. These compounds exhibit a uniq
ue enantiotropic crystal-B-hexatic-B-smectic-A phase sequence with no
evidence of herringbone order. The hexatic order parameter Cg changes
in the hexatic phase with critical exponent beta=0.15+/-0.03. Temperat
ure dependence of the in-plane positional order correlation length sug
gests a strongly first-order hexatic-B to crystal-B phase transition w
ith indiscernible enthalpy change.