A cavity theory is used to relate the dose deposited in the cavity (se
nsitive volume of the detector) to that in the surrounding medium whic
h may be of different atomic number or composition. Burlin proposed a
general cavity theory to include all cavity sizes. The Burlin theory i
gnores all secondary-electron scattering effects which results in larg
e discrepancies in dose to the cavity compared with the experimental r
esults in high atomic number media. Kearsley proposed a new general ca
vity theory which includes secondary-electron scattering at the cavity
boundary. The Kearsley theory showed excellent agreement with experim
ental results for Co-60 gamma-rays but poor correlation for 10 MV x-ra
ys. The Kearsley theory has numerous parameters and the magnitude of t
he input parameters is arbitrary; therefore the dose to the cavity dep
ends on the choice of parameters. We have developed a new cavity theor
y which includes secondary-electron backscattering from the medium int
o the cavity. The strengths of this proposed theory are that it contai
ns few parameters and a methodical way of determining the magnitude of
the parameters experimentally. The proposed theory gives better agree
ment with experimental results in lithium fluoride thermoluminescence
dosimeters for Co-60 gamma-rays and 10 MV x-rays in aluminium, copper
and lead than do the Burlin and Kearsley cavity theories.