2,2'-BIPYRIDINIUM CHLOROCHROMATE M-CHLOROPERBENZOIC ACID-MEDIATED CLEAVAGE OF CYCLIC ACETALS TO HYDROXYESTERS/

Authors
LUZZIO FA BOBB RA
Citation
Fa. Luzzio et Ra. Bobb, 2,2'-BIPYRIDINIUM CHLOROCHROMATE M-CHLOROPERBENZOIC ACID-MEDIATED CLEAVAGE OF CYCLIC ACETALS TO HYDROXYESTERS/, Tetrahedron letters, 38(10), 1997, pp. 1733-1736
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
10
Year of publication
1997
Pages
1733 - 1736
Database
ISI
SICI code
0040-4039(1997)38:10<1733:2CMAC>2.0.ZU;2-#
Abstract
Benzylidene acetals are cleaved to hydroxyesters by means of a reagent system composed of 2,2'-bipyridinium chlorochromate (BPCC) and m-chlo roperbenzoic acid. Oxidative cleavage of a 4,6-O-benzylidene glucose d erivative affords a 6-O-benzoyl derivative. (C) 1997 Elsevier Science Ltd.