CHEMOSELECTIVE ADDITION OF GRIGNARD-REAGENTS TO ALKOXYCARBONYLALKYL-N-IMIDAZOLIUM-N-METHYL AMIDES - SYNTHESIS OF 4-OXO AND HOMOLOGOUS ESTERS

Authors
DELASHERAS MA VAQUERO JJ GARCIANAVIO JL ALVAREZBUILLA J
Citation
Ma. Delasheras et al., CHEMOSELECTIVE ADDITION OF GRIGNARD-REAGENTS TO ALKOXYCARBONYLALKYL-N-IMIDAZOLIUM-N-METHYL AMIDES - SYNTHESIS OF 4-OXO AND HOMOLOGOUS ESTERS, Tetrahedron letters, 38(10), 1997, pp. 1817-1820
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
10
Year of publication
1997
Pages
1817 - 1820
Database
ISI
SICI code
0040-4039(1997)38:10<1817:CAOGTA>2.0.ZU;2-I
Abstract
A method for the synthesis of Core and homologous esters is achieved b y metalation of alkoxycarbonylalkyl-N-imidazolium-N-methyl amides with lequiv of LDA followed by highly chemoselective addition of 1 equiv o f a Grignard reagent. (C) 1997 Elsevier Science Ltd.