OXOVANADIUM(V)-INDUCED TANDEM NUCLEOPHILIC-ADDITION AND OXIDATIVE RING-OPENING TRANSFORMATION

Authors
HIRAO T FUJII T TANAKA T OHSHIRO Y
Citation
T. Hirao et al., OXOVANADIUM(V)-INDUCED TANDEM NUCLEOPHILIC-ADDITION AND OXIDATIVE RING-OPENING TRANSFORMATION, Synlett, (10), 1994, pp. 845-846
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
10
Year of publication
1994
Pages
845 - 846
Database
ISI
SICI code
0936-5214(1994):10<845:OTNAOR>2.0.ZU;2-A
Abstract
Oxovanadium(V) compounds served as Lewis acid with one-electron oxidat ion capability in the reaction of cyclobutanone with silyl enol ethers to give 6-chloro-1,3-diketones and 2-tetrahydrofurylidene ketones via nucleophilic addition and oxidative ring cleavage.