K. Kumbilieva et al., JOINT EFFECTS OF DIFFUSION RESISTANCE AND CATALYST DEACTIVATION ON THE SELECTIVITY OF COMPLEX-REACTIONS PROCEEDING VIA DIFFERENT MECHANISMS, Applied catalysis. A, General, 118(2), 1994, pp. 199-215
The analysis presented is devoted to kinetic problems connected with t
he joint effects of catalyst deactivation and mass transfer on the sel
ectivity and optimal process design of catalytic processes following d
ifferent reaction schemes. The relation between the process mechanism
and the changes of selectivity with the drop of conversion is modelled
for the presence and absence of intraparticle diffusion.