CRYSTAL AND MOLECULAR-STRUCTURE AND REACTIVITY OF JACOBSEN EPOXIDATION CATALYST N,N'-DI(3-T-BUTYL-5-METHYL SALICYLIDENE)CYCLOHEXANEDIAMINE MANGANESE(III)CHLORIDE-CENTER-DOT-MECN

Authors
RISPENS MT MEETSMA A FERINGA BL
Citation
Mt. Rispens et al., CRYSTAL AND MOLECULAR-STRUCTURE AND REACTIVITY OF JACOBSEN EPOXIDATION CATALYST N,N'-DI(3-T-BUTYL-5-METHYL SALICYLIDENE)CYCLOHEXANEDIAMINE MANGANESE(III)CHLORIDE-CENTER-DOT-MECN, Recueil des travaux chimiques des Pays-Bas, 113(9), 1994, pp. 413
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Recueil des travaux chimiques des Pays-Bas → ACNP
ISSN journal
01650513
Volume
113
Issue
9
Year of publication
1994
Database
ISI
SICI code
0165-0513(1994)113:9<413:CAMARO>2.0.ZU;2-F
Abstract
The molecular structure of Jacobsen epoxidation catalyst N,N'-di(3-t-b utyl-5-methyl salicylidene)cyclohexanediamine manganese(III)chloride M eCN 1 is determined by single crystal X-ray and UV-Vis analysis. The e poxidation of dihydronaphthalene and dimethylchromene with amorphous a nd crystalline catalyst gave comparable enantiomeric excesses of 69 % and 92 % respectively.