K. Nagai et al., BROMINATION AND GAS-PERMEABILITY OF POLY(1-TRIMETHYLSILYL-1-PROPYNE) MEMBRANE, Journal of applied polymer science, 54(9), 1994, pp. 1207-1217
The bromination of poly(1-trimethylsilyl-1-propyne) (PMSP) was carried
out by immersing a PMSP membrane in bromine water at 25-degrees-C. Th
e bromine mainly reacted at the carbon-carbon double bonds in the back
bone chain, and carbon-carbon single bonds were produced, which was de
termined from the infrared (IR) and ultraviolet (UV)-visible analyses.
The glass transition temperature of the PMSP is above 350-degrees-C,
but a new endothermic peak appeared between 50 and 80-degrees-C in the
differential scanning calorimetry (DSC) curves of all brominated PMSP
s. The permeability for 12 gases in the PMSP membrane and its brominat
ed membranes was investigated between 30 and 90-degrees-C below 1 atm.
With increasing bromine content in the membrane, the permeability coe
fficient for all gases decreased together with the diffusion coefficie
nt, and the ideal separation factor for the industrially important gas
pairs increased at 30-degrees-C. A distinct change in slopes at near
the endothermic temperature determined by the DSC analysis was observe
d in Arrhenius plots of the permeability coefficients in all brominate
d PMSP membranes. (C) 1994 John Wiley & Sons, Inc.