REGIO-SELECTIVITY AND CHEMO-SELECTIVITY OF ADAMANTANE HALOGENATION BYGIF-BARTON AND METALLOPORPHYRIN CATALYSIS AND BY CLASSICAL FREE-RADICAL REACTIONS

Authors
MINISCI F FONTANA F ZHAO LH BANFI S QUICI S
Citation
F. Minisci et al., REGIO-SELECTIVITY AND CHEMO-SELECTIVITY OF ADAMANTANE HALOGENATION BYGIF-BARTON AND METALLOPORPHYRIN CATALYSIS AND BY CLASSICAL FREE-RADICAL REACTIONS, Tetrahedron letters, 35(43), 1994, pp. 8033-8036
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
43
Year of publication
1994
Pages
8033 - 8036
Database
ISI
SICI code
0040-4039(1994)35:43<8033:RACOAH>2.0.ZU;2-B
Abstract
The halogenation of adamantane by CBrCl3 with Gif-Barton and metallopo rphyrin catalysis is compared with classical free-radical halogenation s (Br-2, NBS, t-BuOCl, R(2)NCl) and with the behaviour of simple alkan es (n-hexane, 2,3-dimethylbutane, cyclohexane); the free-radical mecha nism is discussed.