IMPROVED SYNTHESES AND STRUCTURE OF N)(4)](CLO4)(3)CENTER-DOT-2CH3COOH-CENTER-DOT-2H2O

Authors
MANCHANDA R BRUDVIG GW DEGALA S CRABTREE RH
Citation
R. Manchanda et al., IMPROVED SYNTHESES AND STRUCTURE OF N)(4)](CLO4)(3)CENTER-DOT-2CH3COOH-CENTER-DOT-2H2O, Inorganic chemistry, 33(22), 1994, pp. 5157-5160
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
22
Year of publication
1994
Pages
5157 - 5160
Database
ISI
SICI code
0020-1669(1994)33:22<5157:ISASON>2.0.ZU;2-#
Abstract
We present two new-routes to synthesize [(MnMnIV)-Mn-III(O)(2)(phen)(4 )](ClO4)(3) (1, phen = 1,10-phenanthroline). The crystal structure of 1 shows structurally distinct Mn ions with a Jahn-Teller distorted Mn- III and an undistorted Mn-IV, indicating an electron-localized complex ; the 16-line EPR signal from 1 also shows that this is a trapped-vale nces complex.