Y. Fuchs et M. Lagache, THE CHLORITE TOURMALINE TRANSFORMATION IN NATURAL AND EXPERIMENTAL HYDROTHERMAL ENVIRONMENTS, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 319(8), 1994, pp. 907-913
Alterations leading to borosilicate formation in hydrothermal systems
evolve together with aluminous alterations with the assemblage chlorit
e + calcium-borosilicate in the periphery, then phengite + tourmaline
and, in the core of the hydrothermal system, (pyrophylite, andalousite
) + dumortierite. The circulation of a boron-rich fluid induces the tr
ansformation of chlorite into tourmaline. This reaction was reproduced
using a mixture of chlorite, alkali-feldspar and H3BO3 in sealed gold
tubes introduced into pressure vessels at temperatures from 400 to 70
0-degrees-C. It seems to be a general reaction in such an environment.