MORPHOLOGICAL-STUDY OF HYDROGEN PERMEABLE PD MEMBRANES

This work deals with the relationship between morphology of electroles sly deposited Pd membranes and hydrogen permeation. Both concentrated and dilute Pd containing electroless baths were examined. Scanning ele ctron microscopy and X-ray diffraction line broadening analyses reveal ed the formation of different morphologies due to the deposition kinet ics. Crystallization aspects in electroless deposition were discussed. Loosely packed palladium particles being about 420 nm in diameter wer e formed by repeated depositions from the dilute bath. Dense palladium membranes with primary particle sizes of about 11 nm were deposited f rom the concentrated bath. Only the latter composite membrane was perm selective to hydrogen.