NOVEL SILYLATING AGENTS EMPLOYING 4-PENTENYL SILYL ETHERS

Citation
C. Colombier et al., NOVEL SILYLATING AGENTS EMPLOYING 4-PENTENYL SILYL ETHERS, Tetrahedron letters, 35(44), 1994, pp. 8167-8170
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
44
Year of publication
1994
Pages
8167 - 8170
Database
ISI
SICI code
0040-4039(1994)35:44<8167:NSAE4S>2.0.ZU;2-N
Abstract
Nonsymmetrical silaketals R'OSiR(2)OR'' other than R = Me were efficie ntly prepared by the activation of 4-pentenyl silyl ethers with IDCP i n the presence of an alcohol. In addition, trialkylsilyl ethers could be prepared from the corresponding trialkylsilyl pentenyl ether.