Separate headspace samplings of Brassica napus flowers and leaves in s
itu showed that six volatiles were emitted from the flowers only, 12 c
ompounds were common to both flowers and leaves, and 11 compounds were
emitted from the leaves only. The average emission of floral volatile
s was 45 ng per flower per hr. Floral rhythmic emission was shown for
sabinene and limonene, both emitted from flowers and leaves. In contra
st, no rhythm of emission was detected for the major compounds emitted
from the flowers only, i.e. alpha-farnesene, linalool and 3-carene. A
rhythmic nature of emission could not be discerned after transfer to
constant environmental conditions. The significance of the floral vola
tiles in plant-insect relationships is discussed.