E. Bouveresse et al., CALIBRATION TRANSFER ACROSS NEAR-INFRARED SPECTROMETRIC INSTRUMENTS USING SHENKS ALGORITHM - EFFECTS OF DIFFERENT STANDARDIZATION SAMPLES, Analytica chimica acta, 297(3), 1994, pp. 405-416
In this paper, transfer of calibration models between near-infrared sp
ectrometric instruments using three different standardisation sets is
described. The first set contains samples which are very similar to th
e agricultural samples from three different sets to be analysed, the s
econd set contains generic standards, and the third one contains pure
organic and inorganic chemicals. To test the accuracy of each standard
isation, root mean square errors and correlation coefficients are comp
uted before and after standardisation. To test the predictive ability,
standard error of prediction for the three different prediction sets
are also computed before and after standardisation. For standardisatio
n, Shenk's algorithm is used: a description of this algorithm is given
.