POSSIBILITIES FOR GRAPHIC REPRESENTATION OF MULTIFACTOR SIMPLEX OPTIMIZATION

Authors
Citation
Al. Molinero, POSSIBILITIES FOR GRAPHIC REPRESENTATION OF MULTIFACTOR SIMPLEX OPTIMIZATION, Analytica chimica acta, 297(3), 1994, pp. 417-425
Citations number
13
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032670
Volume
297
Issue
3
Year of publication
1994
Pages
417 - 425
Database
ISI
SICI code
0003-2670(1994)297:3<417:PFGROM>2.0.ZU;2-H
Abstract
The progress of a multifactor simplex optimisation algorithm has been plotted in a visual mode, after a reduction in the number of factors u sing the statistic principal component analysis method. The effectiven ess of the proposed graphic representation has been evaluated when app lied to simplex previously published optimisation methods such as: col orimetric determination of cholesterol, flow-injection spectrophotomet ric determination of promethazine and synthesis of an industrial pyraz olone. The procedure has also been applied to develop new experimental analytical methods like the determination of arsenic trichloride by i nductively coupled plasma atomic emission spectrometry.