CHARACTERIZATION OF HYDROXYL-TERMINATED POLYBUTADIENE .6. REACTIONS WITH SOLVENT DURING POLYMERIZATION

Authors
VILAR WD MENEZES SMC SEIDL PR
Citation
Wd. Vilar et al., CHARACTERIZATION OF HYDROXYL-TERMINATED POLYBUTADIENE .6. REACTIONS WITH SOLVENT DURING POLYMERIZATION, Polymer bulletin, 38(3), 1997, pp. 311-318
Citations number
25
Categorie Soggetti
Polymer Sciences
Journal title
Polymer bulletin → ACNP
ISSN journal
01700839
Volume
38
Issue
3
Year of publication
1997
Pages
311 - 318
Database
ISI
SICI code
0170-0839(1997)38:3<311:COHP.R>2.0.ZU;2-L
Abstract
H-1 and C-13 NMR spectra were used to study the structure of hydroxyl- terminated polybutadiene (HTPB) obtained by using hydrogen peroxide as initiator and an alcohol as solvent. This alcohol was introduced into the polymer chain, forming a hydroxylated end group. The subject has aroused some argument in the literature and is considered further in o ur discussion of reaction mechanisms.