ENANTIOSELECTIVE SYNTHESIS OF THE C-11-C24 SEGMENT OF MACROLACTIN-A VIA ORGANOIRON METHODOLOGY

Authors
PRAHLAD V DONALDSON WA
Citation
V. Prahlad et Wa. Donaldson, ENANTIOSELECTIVE SYNTHESIS OF THE C-11-C24 SEGMENT OF MACROLACTIN-A VIA ORGANOIRON METHODOLOGY, Tetrahedron letters, 37(51), 1996, pp. 9169-9172
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
51
Year of publication
1996
Pages
9169 - 9172
Database
ISI
SICI code
0040-4039(1996)37:51<9169:ESOTCS>2.0.ZU;2-Y
Abstract
The enantioselective synthesis of the Fe(CO)(3) complexed C11-C24 segm ent of macrolactin A has been accomplished from rac-(methyl 6-oxo-2,4- hexadienoate)Fe(CO)(3) in 11 steps (>50% ee). Copyright (C) 1996 Elsev ier Science Ltd