TRANSITION-METAL SILYL COMPLEXES, .52. FO RMATION OF COPPER SILYL ANDSTANNYL COMPLEXES BY REACTION OF [PH3PCUH]6 WITH HER3 (E=SI, SN)

Authors
SCHUBERT U MAYER B RUSS C
Citation
U. Schubert et al., TRANSITION-METAL SILYL COMPLEXES, .52. FO RMATION OF COPPER SILYL ANDSTANNYL COMPLEXES BY REACTION OF [PH3PCUH]6 WITH HER3 (E=SI, SN), Chemische Berichte, 127(11), 1994, pp. 2189-2190
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
11
Year of publication
1994
Pages
2189 - 2190
Database
ISI
SICI code
0009-2940(1994)127:11<2189:TSC.FR>2.0.ZU;2-0
Abstract
[Ph3PCuH]6 was used as a source for the Ph3PCu fragment to prepare cop per stannyl and silyl complexes. Reaction of [Ph3PCuH]6 with HSnPh3, H SiPh3 or HSiClPh2, respectively, and two equivalents of PPh3 yielded t he complexes (Ph3P)3CuER3 (ER3 = SnPh3, SiPh3, SiClPh2).