NEW CONCAVE 1,10-PHENANTHROLINES - CATALYSTS FOR THE ALCOHOL ADDITIONTO KETENES AND LIGANDS IN TRANSITION-METAL COMPLEXES

Authors
LUNING U",MU,"MULLER M GELBERT M PETERS K VONSCHNERING HG KELLER M
Citation
M. Luning U",mu,"muller et al., NEW CONCAVE 1,10-PHENANTHROLINES - CATALYSTS FOR THE ALCOHOL ADDITIONTO KETENES AND LIGANDS IN TRANSITION-METAL COMPLEXES, Chemische Berichte, 127(11), 1994, pp. 2297-2306
Citations number
36
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
11
Year of publication
1994
Pages
2297 - 2306
Database
ISI
SICI code
0009-2940(1994)127:11<2297:NC1-CF>2.0.ZU;2-S
Abstract
By bridging tetrahydroxy-1,10-phenanthrolines 9 by ditosylates 10 or d iiodides 11 concave 1,10-phenanthrolines 1 were synthesized. Their con cave shape was proven by X-ray analyses of 1a and 1c, their basicities were determined by photometric titrations. Compounds 1a-g are active in the base-catalyzed addition of alcohols to ketenes and form stable metal ion complexes with transition metal salts.