HIGH-TEMPERATUUE STABILITY OF CA2ZRSI4O12

Authors
JACOB KT WASEDA Y
Citation
Kt. Jacob et Y. Waseda, HIGH-TEMPERATUUE STABILITY OF CA2ZRSI4O12, Journal of the American Ceramic Society, 77(11), 1994, pp. 3033-3035
Citations number
23
Categorie Soggetti
Material Science, Ceramics
Journal title
Journal of the American Ceramic Society → ACNP
ISSN journal
00027820
Volume
77
Issue
11
Year of publication
1994
Pages
3033 - 3035
Database
ISI
SICI code
0002-7820(1994)77:11<3033:HSOC>2.0.ZU;2-I
Abstract
The standard Gibbs free energy of formation of orthorhombic Ca2ZrSi4O1 2 from component oxides ZrO2 (monoclinic), CaO (rock salt), and SiO2 ( quartz) has been determined in the temperature range 973 to 1273 K usi ng a solid-state cell incorporating single-crystal CaF2 as the electro lyte: Delta G(f) degrees = -219930 + 11.77T (+/- 1500) J.mol(-1) This is the only quantitative information now available on the stability of Ca2ZrSi4O12.