The charged state of implanted positive muons, Mu(+/-), formed at high
temperatures undergoes fast spin relaxation in both Si and Ge under i
llumination due to a cyclic charge-exchange reaction with photoinduced
carriers. In Si, the neutral tetrahedral interstitial muonium state (
Mu(T)(0)) also collides effectively with carriers to induce reaction,
while in Ge the neutral state is unreactive. In particular, in Si at l
ow temperatures, the Mu(T)(0) center is rapidly converted into bond ce
nter muonium (Mu(BC)(0)) With supervening fast spin relaxation under i
llumination.