SYNTHESIS AND X-RAY STRUCTURE STUDIES OF COMPLEX [CU(O-PHENANTHROLINE)2 (SACCHARIN)].(SACCHARIN).2H2O

Citation
Yg. Zhang et al., SYNTHESIS AND X-RAY STRUCTURE STUDIES OF COMPLEX [CU(O-PHENANTHROLINE)2 (SACCHARIN)].(SACCHARIN).2H2O, Crystal research and technology, 29(7), 1994, pp. 975-980
Citations number
6
Categorie Soggetti
Crystallography
ISSN journal
02321300
Volume
29
Issue
7
Year of publication
1994
Pages
975 - 980
Database
ISI
SICI code
0232-1300(1994)29:7<975:SAXSSO>2.0.ZU;2-X
Abstract
The title compound has been synthesized and its crystal structure dete rmined at room temperature, M(r) = 824.34, triclinic, space group P-1( 2), a = 13.622(4), b = 13.770(4), c = 11.167(3) angstrom; alpha = 104. 83(2), beta = 110.01(2), gamma = 62.04(2) degree; U = 1727.0(9) angstr om3, Z = 2, D(calc) = 1.59 g/cm3. The final R is 0.066 for 3299 indepe ndent observed reflections with I greater-than-or-equal-to 3sigma(I). The crystal structure consists of repeated [Cu(o-phen)2(sac)]+ cations , non-coordinated saccharin anion and two lattice water. And the centr al ion Cu2+ forms a trigonal-bipyramidal stereochemistry.