TERT-BUTYLAMMONIUM CONDENSED VANADATES .1. HEXAKIS (TERT-BUTYLAMMONIUM DECAVANADATE OCTAHYDRATE)

Authors
AVERBUCHPOUCHOT MT
Citation
Mt. Averbuchpouchot, TERT-BUTYLAMMONIUM CONDENSED VANADATES .1. HEXAKIS (TERT-BUTYLAMMONIUM DECAVANADATE OCTAHYDRATE), European journal of solid state and inorganic chemistry, 31(7), 1994, pp. 557-565
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
31
Issue
7
Year of publication
1994
Pages
557 - 565
Database
ISI
SICI code
0992-4361(1994)31:7<557:TCV.H(>2.0.ZU;2-B
Abstract
[(CH3)3CNH3]6V10O28.8H2O provides a new example of an organic-cation d ecavanadate. This salt is monoclinic, P2(1)/c, with Z = 2 and the foll owing unit-cell dimensions: a = 11.684(1), b = 26.367(3), c = 10.535(1 ) angstrom, beta = 114.08(3)-degrees. Its atomic arrangement refined w ith a final R value of 0.038 for a set of 7056 independent reflections is mainly characterized by a layer organization of centrosymmetrical [V10O28]6- anions and [(CH3)3CNH3]+ groups. The three-dimensional hydr ogen-bond scheme is given.