REGIOSELECTIVE FUNCTIONALIZATION OF BIS(TRIMETHYLSILY)METHYLIMINES WITH ELECTROPHILES

Authors
RICCI A GUERRINI A SECONI G MORDINI A CONSTANTIEUX T PICARD JP AIZPURUA JM PALOMO C
Citation
A. Ricci et al., REGIOSELECTIVE FUNCTIONALIZATION OF BIS(TRIMETHYLSILY)METHYLIMINES WITH ELECTROPHILES, Synlett, (11), 1994, pp. 955-957
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1994
Pages
955 - 957
Database
ISI
SICI code
0936-5214(1994):11<955:RFOBW>2.0.ZU;2-L
Abstract
A very good control of the regioselectivity occurs in the deprotonatio n of imino derivatives of bis(trimethylsilyl) methylamine (BSMA) follo wed by quenching with electrophiles. Functionalization at C-1, C-3 or C-4 takes place selectively depending on the nature of the electrophil e and of the base employed. This methodology provides an entry to a wi de class of novel, functionalized, silylated imino derivatives.