The electron field emission from diamond surfaces is investigated theo
retically using a model consisting of the projection of the energy ban
d surfaces in the [111], [110], and [100] emission directions. The eff
ect of the negative electron affinity, the band bending, the image int
eraction, and surface states is examined in detail. It is found that t
he conventional theory of electron field emission applied to crystalli
ne diamond cannot explain the measured high-current emission at low fi
elds. We postulate two subbands in the intrinsic band gap, which may b
e generated by defects or impurities. With reasonable band parameters,
the calculated I-V characteristics agree with experimental data. (C)
1994 American Institute of Physics.