M. Danielewski et W. Krzyzanski, THE CONSERVATION OF MOMENTUM AND ENERGY IN OPEN SYSTEMS - DIFFUSIONALAPPROACH TO THE MASS-TRANSPORT IN SOLIDS, Physica status solidi. a, Applied research, 145(2), 1994, pp. 351-361
The Navier-Stokes equations do not describe the mixing of mass in a co
ntinuous medium. In this work the motion of a mixture in which mass fl
ows from the region of higher mass density to the lower one is analyze
d. In such a case the mass is transported as a result of pressure, vis
cosity, external forces, and diffusion. The motion of a continuous med
ium in which diffusional flux of mass occurs is considered. The moment
um balance of a mixture in which diffusion is considered causes a new
term to appear in the Navier-Stokes equation. Apart from terms respons
ible for pressure, viscosity, and external forces there is the diffusi
onal one. It is analyzed whether the internal energy of mixture depend
s on diffusion. The conclusion is that diffusional flux does not chang
e the internal energy of mixture. The specific initial conditions for
pure diffusion are defined and it is elucidated that the diffusion is
described by the well-known equation of diffusion.