STRUCTURAL STUDIES ON OXALATOTRIORGANOSTANNATES - CRYSTAL-STRUCTURE OF TRIMETHYLSULFONIUM CATENA-O, O'-OXALATOTRIPHENYLSTANNATE

Authors
NG SW DAS VGK LUO BS MAK TCW
Citation
Sw. Ng et al., STRUCTURAL STUDIES ON OXALATOTRIORGANOSTANNATES - CRYSTAL-STRUCTURE OF TRIMETHYLSULFONIUM CATENA-O, O'-OXALATOTRIPHENYLSTANNATE, Zeitschrift fur Kristallographie, 209(11), 1994, pp. 882-884
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Zeitschrift fur Kristallographie → ACNP
ISSN journal
00442968
Volume
209
Issue
11
Year of publication
1994
Pages
882 - 884
Database
ISI
SICI code
0044-2968(1994)209:11<882:SSOO-C>2.0.ZU;2-D
Abstract
The crystal structure of trimethylsulfonium oxalatotriphenylstannate, C23H24O4SSn, synthesized from the metathetical reaction of trimethylsu lfonium iodide, silver oxalate and triphenyltin chloride in methanol, consists of [(CH3)3S]+ ions interspersed among the linear [(C6H5)3SnO2 CCO2]n(n-) chains that are constructed from [O2CCO2]2- dianions bonded axially to planar [(C6H5)3Sn]+ (Sn - O = 2.220(3) angstrom, SIGMA C - Sn - C = 360.0(4)-degrees) cations.