THE REARRANGEMENT OF ALPHA-IMINO-THIOALDEHYDES INTO DIHYDRO-1,3-THIAZOLES

Authors
ARNAUD R PELLOUXLEON N RIPOLL JL VALLEE Y
Citation
R. Arnaud et al., THE REARRANGEMENT OF ALPHA-IMINO-THIOALDEHYDES INTO DIHYDRO-1,3-THIAZOLES, Tetrahedron letters, 35(45), 1994, pp. 8389-8392
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
45
Year of publication
1994
Pages
8389 - 8392
Database
ISI
SICI code
0040-4039(1994)35:45<8389:TROAID>2.0.ZU;2-#
Abstract
alpha-Imino-thioaldehydes were generated by retro-Diels-Alder reaction under flash vacuum thermolysis conditions. They were found to be unst able and cyclized to 2,3-dihydro-1,3-thiazoles. This cyclization was i nvestigated by ab initio calculations.